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TiO₂ Information

What is TiO₂

TiO₂ is an important inorganic compound that is widely used in daily life. It is a representative white pigment used for plastics, paints, rubbers, and papers. The economic development of a country is sometimes measured by the usage of TiO₂ per person.

TiO₂ is a very stable material physically and chemically, and has superior coverage and staining power because it has the highest refractive index among the white pigments, as well as accurate particle sizes and dispersibility. It is used to remove gloss from chemical textiles, to improve the abrasion resistance of chemical textiles, and for pigmentation. It is also widely used in various other areas, such as electronic materials, a glass, and welding rod coverings, based on its electronic characteristics.

As new products utilizing the characteristics of TiO₂ are currently rapidly being developed and applied to various areas, the competition among countries is becoming increasingly fierce. The representative products are catalysts and photocatalysts using nano-type products.

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History of TiO₂

In the 18th century. Reverend William Gregor, an amateur mineralogist, found a white metallic oxide unknown to contemporary chemists from the local magnetic black sands, containing 50% white metallic oxide. In 1795, Martin H. Klaproth confirmed the contents of the rutile deposits and named the oxide element titanium after the mythological Titans, the first sons of Earth in a Greek legend. The name stuck.

As researches on the manufacture of Ti (titanium metal) and TiO₂ (titanium dioxide) have been conducted since the 19th century, W. J. Kroll established an engineering method for titanum metal. Anatase TiO₂ was commercialized by Fabriques de Produits Chimques de Thann of France in 1923, through multiple researches, and has been continuously developed technically.

At present, the TiO₂ that is being commercially distributed is largely divided into two categories: rutile and anatase. Rutile was first manufactured by NL Industries (U.S.) at the end of 1940.

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Perspectives of TiO₂

TiO₂ will be continuously developed as its usage is increasing due to the ongoing industrial development. A wide array of products using TiO₂ as well as white pigment are being developed and applied, which will increase the manufacture and consumption of high-value-added derivatives. The representative product is the photocatalyst TiO₂, which is present around us. The photocatalyst TiO₂ is now being applied to daily life due to the rapid technical development and expansion of its applications. Its relevant market size will also significantly grow.

Its annual global output and consumption is about 5 million tons per year, and prominent chemical groups, such as DuPont, Crystal, and Tronox, are manufacturing it. In South Korea, Cosmo Chemical is the sole manufacturer of TiO₂ and thus competes with global firms.

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  • 황산법은 광석을 건조, 분쇄 후 황산과 반응시켜 용해한다 FeTiO₃ + 2H₂SO₄에서 FeSO₄ + TiOSO₄ + 2H₂O로 변환한다
  • Ti와 Fe성분으로 이루어진 황산염수용액에서 Fe³ 를 Fe² 로 모두 환원한 후 여과·냉각결정하여 황산 제1철(FeSO₄ 7H₂O)을 분리하고, 액을 농축한 후 물을 이용한 가수분해(Hydrolysis)를 통하여 불용성의 백색 함수산화티탄을 만든다.TiOSO₄ + 2H₂O에서TiO(OH)₂ + H₂SO₄로 변환한다

 Sulfate Process

  • The ore is first dried, ground, and classified, and is then dissolved in a sulfate solution FeTiO₃ + 2H₂SO₄에서 FeSO₄ + TiOSO₄ + 2H₂O
  • After the deoxidation of Fe³+ and Fe²+ in a sulfate solution consisting of Ti and Fe elements, the solution is then filtered and cooled to crystallize the coarse Ferrous Sulfate Solution heptahydrate (FeSo4 7H₂O), which is separated from the process. The solution is hydrolyzed to produce insoluble white hydrous titanium oxide.TiOSO₄ + 2H₂O에서TiO(OH)₂ + H₂SO₄
  • This is an important process for deciding the first particle size and distribution of hydrous titanium oxide, which is needed to come up with good products with appropriate particle sizes in the hydrolysis process. The pulp is extensively washed to remove the residual traces of metallic impurities. The washed pulp is then calcinated in a rotary kiln, and ground. Then the final products are manufactured. TiO(OH)₂에서 TiO₂ + H₂O
  • In the sulfate process, rutile can be produced as using catalyst added before calcinations or on additives in hydrolysis step. Thus, this process can produce either anatase or rutile crystal forms depending on additives used prior to calcinations differently from the chloride process.
    1. Drying,Grinding
    2. Dissolving,Deoxidizing
    3. Precipitating,filtering
    4. Crystallizing,separating
    5. Grinding,packing
    6. Washing,additives
    7. Concentrating,hydrolyzing
    8. TiO₂

    Note: The grades of rutile and anatase are diversified by purpose, by coating with aluminum (AI) or silica (Si) in the post-treatment process.